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{{Infobox_Scientist| name=Hermann Staudinger| image=Hermann Staudinger.jpg| birth_date = | birth_place = Worms, Germany, Grand Duchy of Hesse,
German Empire, [Germany| alma_mater = [University of Halle
[University of KarlsruheETH ZürichUniversity of Freiburg| doctoral_students = [Lavoslav Ružička| prizes = [Nobel Prize in Chemistry, [1881 –
September 8,
1965) was a
Germany chemist who demonstrated the existence of
macromolecules which he characterized as polymers. For this work he received the 1953 Nobel Prize in Chemistry. He is also known for his discovery of ketenes and of the
Staudinger reaction.
Early work
Hermann Staudinger was born in 1881 in Worms, Germany. After receiving his Ph.D. from the University of Halle in 1903, Staudinger took a position at the University of Strasbourg. It was here that he discovered the ketenes, a family of molecules characterized by the general form depicted in
Figure 1. Ketenes would prove a synthetically-important intermediate for the production of yet-to-be-discovered antibiotics such as
penicillin and
amoxicillin.
In 1907, Staudinger began an assistant professorship at the University of Karlsruhe where he successfully isolated a number of useful organic compounds (including a synthetic coffee flavoring) as more completely reviewed by Mülhaupt.
The Staudinger reaction
In 1912, Staudinger took on a new position at the
Swiss Federal Institute of Technology in
Zurich, Switzerland. One of his earliest discoveries came in 1919, when he and colleague Meyer reported that azides react with
triphenylphosphine to form phosphazide (
Figure 2).Staudinger, H.; Meyer, J.
Helv. Chim. Acta 1919,
2, 635. This reaction – commonly referred to as the Staudinger reaction – produces a high phosphazide yield.
Polymer chemistry
While at Karlsruhe and later, Zurich, Staudinger began research in the chemistry of rubber, for which very high molecular mass had been measured by the physical methods of
François-Marie Raoult and
Jacobus Henricus van 't Hoff. Contrary to prevailing ideas (see below), Staudinger proposed in a landmark paper published in 1920 that rubber and other polymeric substances such as starch,
cellulose and
proteins are long chains of short repeating molecular units linked by covalent bonds.Staudinger, H.
Ber. Deut. Chem. Ges. 1920,
53, 1073. In other words, polymers are like chains of paper clips, made up of small constituent parts linked from end to end (
Figure 3).
At the time leading organic chemists such as
Hermann Emil Fischer and Heinrich Wieland.Feldman, S. D.; Tauber, A. I.
Bull. Hist. Med. 1997,
17(4), 623-650. believed that the measured high molecular weights were only apparent values caused by the aggregation of small molecules into
colloids. At first the majority of Staudinger’s colleagues refused to accept the possibility that small molecules could link together covalently to form high-molecular weight compounds. As Mülhaupt aptly notes, this is due in part to the fact that molecular structure and bonding theory were not fully understood in the early 20th century.
Further evidence to support Staudinger’s hypothesis emerged in the 1930s. High molecular weights of polymers were confirmed by
osmotic pressure, and also by Staudinger’s measurements of
viscosity in solution. The X-ray diffraction studies of polymers by Herman Mark provided direct evidence for long chains of repeating molecular units. And the synthetic work led by Wallace Carothers demonstrated that polymers such as
nylon and
polyester could be prepared by well-understood organic reactions.
Legacy
Staudinger’s groundbreaking elucidation of the nature of the high-molecular weight compounds he termed
Makromoleküle paved the way for the birth of the field of polymer chemistry.Staudinger, H.
Trans. Faraday Soc. 1933,
29, 18-32. Staudinger himself saw the potential for this science long before it was fully realized. “It is not improbable,” Staudinger smartly commented in 1936, “that sooner or later a way will be discovered to prepare artificial fibers from synthetic high-molecular products, because the strength and elasticity of natural fibers depend exclusively on their macro-molecular structure – i.e., on their long thread-shaped molecules.”Staudinger, H.
Trans. Faraday Soc. 1936,
32, 323-335. Staudinger founded the first polymer chemistry journal in 1940,Meisel, I.; Mülhaupt, R.
Macromol. Chem. Phys. 2003,
204, 195-206. and in 1953 received the Nobel Prize in Chemistry for “his discoveries in the field of macromolecular chemistry.” The Nobel Prize in Chemistry 1953 (accessed Mar 2006). His pioneering research has afforded the world myriad plastics, textiles, and other polymeric materials which make consumer products more affordable, attractive, and fun.
See also
References
-
-
External links
- Staudinger’s life and career.
{{Infobox_Scientist| name=Hermann Staudinger| image=Hermann Staudinger.jpg| birth_date = | birth_place = Worms, Germany, Grand Duchy of Hesse,German Empire, [Germany| alma_mater = [University of Halle
[University of Karlsruhe
ETH Zürich
University of Freiburg| doctoral_students = [Lavoslav Ružička| prizes = [Nobel Prize in Chemistry, [1881 – September 8, 1965) was a Germany chemist who demonstrated the existence of macromolecules which he characterized as polymers. For this work he received the 1953 Nobel Prize in Chemistry. He is also known for his discovery of ketenes and of the Staudinger reaction.
Early work
Hermann Staudinger was born in 1881 in Worms, Germany. After receiving his Ph.D. from the University of Halle in 1903, Staudinger took a position at the University of Strasbourg. It was here that he discovered the ketenes, a family of molecules characterized by the general form depicted in Figure 1. Ketenes would prove a synthetically-important intermediate for the production of yet-to-be-discovered antibiotics such as penicillin and amoxicillin.
In 1907, Staudinger began an assistant professorship at the University of Karlsruhe where he successfully isolated a number of useful organic compounds (including a synthetic coffee flavoring) as more completely reviewed by Mülhaupt.
The Staudinger reaction
In 1912, Staudinger took on a new position at the Swiss Federal Institute of Technology in Zurich, Switzerland. One of his earliest discoveries came in 1919, when he and colleague Meyer reported that azides react with triphenylphosphine to form phosphazide (Figure 2).Staudinger, H.; Meyer, J. Helv. Chim. Acta 1919, 2, 635. This reaction – commonly referred to as the Staudinger reaction – produces a high phosphazide yield.
Polymer chemistry
While at Karlsruhe and later, Zurich, Staudinger began research in the chemistry of rubber, for which very high molecular mass had been measured by the physical methods of François-Marie Raoult and Jacobus Henricus van 't Hoff. Contrary to prevailing ideas (see below), Staudinger proposed in a landmark paper published in 1920 that rubber and other polymeric substances such as starch, cellulose and proteins are long chains of short repeating molecular units linked by covalent bonds.Staudinger, H. Ber. Deut. Chem. Ges. 1920, 53, 1073. In other words, polymers are like chains of paper clips, made up of small constituent parts linked from end to end (Figure 3).
At the time leading organic chemists such as Hermann Emil Fischer and Heinrich Wieland.Feldman, S. D.; Tauber, A. I. Bull. Hist. Med. 1997, 17(4), 623-650. believed that the measured high molecular weights were only apparent values caused by the aggregation of small molecules into colloids. At first the majority of Staudinger’s colleagues refused to accept the possibility that small molecules could link together covalently to form high-molecular weight compounds. As Mülhaupt aptly notes, this is due in part to the fact that molecular structure and bonding theory were not fully understood in the early 20th century.
Further evidence to support Staudinger’s hypothesis emerged in the 1930s. High molecular weights of polymers were confirmed by osmotic pressure, and also by Staudinger’s measurements of viscosity in solution. The X-ray diffraction studies of polymers by Herman Mark provided direct evidence for long chains of repeating molecular units. And the synthetic work led by Wallace Carothers demonstrated that polymers such as nylon and polyester could be prepared by well-understood organic reactions.
Legacy
Staudinger’s groundbreaking elucidation of the nature of the high-molecular weight compounds he termed Makromoleküle paved the way for the birth of the field of polymer chemistry.Staudinger, H. Trans. Faraday Soc. 1933, 29, 18-32. Staudinger himself saw the potential for this science long before it was fully realized. “It is not improbable,” Staudinger smartly commented in 1936, “that sooner or later a way will be discovered to prepare artificial fibers from synthetic high-molecular products, because the strength and elasticity of natural fibers depend exclusively on their macro-molecular structure – i.e., on their long thread-shaped molecules.”Staudinger, H. Trans. Faraday Soc. 1936, 32, 323-335. Staudinger founded the first polymer chemistry journal in 1940,Meisel, I.; Mülhaupt, R. Macromol. Chem. Phys. 2003, 204, 195-206. and in 1953 received the Nobel Prize in Chemistry for “his discoveries in the field of macromolecular chemistry.” The Nobel Prize in Chemistry 1953 (accessed Mar 2006). His pioneering research has afforded the world myriad plastics, textiles, and other polymeric materials which make consumer products more affordable, attractive, and fun.
See also
References
-
-
External links
- Staudinger’s life and career.
Hermann Staudinger - Wikipedia, the free encyclopedia
Hermann Staudinger (March 23, 1881 – September 8, 1965) was a German chemist who demonstrated the existence of macromolecules which he characterized as polymers.
Hermann Staudinger - Biography
Biography. Hermann Staudinger was born in Worms on the 23rd of March 1881. His father was Dr. Franz Staudinger. Staudinger was educated in Worms, matriculated in 1899, and ...
Chemistry 1953
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Hermann Staudinger
Hermann Staudinger (1881 - 1965) discovered the structure of polymers. Hermann Staudinger was born at Worms in Germany on 23 March 1881.
Staudinger, Hermann
20th Century. Born: Worms (Germany), 1881 Died: Freiburg (Germany), 1965. After studying in Halle, Darmstadt and München, Staudinger became an assistant in Straßburg (Strasbourg ...
Hermann Staudinger – Wikipedia
Hermann Staudinger (* 23. März 1881 in Worms; † 8. September 1965 in Freiburg im Breisgau) war ein deutscher Chemiker und Nobelpreisträger.
Staudinger, Hermann - Hutchinson encyclopedia article about Staudinger ...
German organic chemist who was awarded the Nobel Prize for Chemistry in 1953 for his discoveries in macromolecular chemistry, of which he was the founder.
Hermann Staudinger - Wikipédia
Hermann Staudinger (23 mars 1881 à Worms - 8 septembre 1965 à Fribourg-en-Brisgau) fut un chimiste allemand. En 1953, il gagna le prix Nobel de chimie pour avoir démontré l ...
Hermann Staudinger
Nobel Winners picture, Nobel Winners Bio ... Hermann Staudinger (1881-1965) German chemist who won the 1953 Nobel Prize for Chemistry for demonstrating that polymers are ...
The Foundation of Polymer Science by Hermann Staudinger
Staudinger's life and career. Hermann Staudinger was born in Worms on the Rhine on March 23, 1881. Because he loved plants and flowers, he studied botany under Georg Klebs at the ...